Head south through to Andorra and pick up the N260/152 east for some classic mountain riding.
There's some great coast roads on the Costa Brava north of Barcelona, especially between Lloret de Mar and Sant Feliu de Guixols.
If time allows head inland a bit to take in the area around Millau, and drop back to the coast when your past Marseille.
The coast road from St Tropez as far as Cannes has some nice twisty bits, although there can be a bit of traffic.
You'll find better roads and a lot less traffic if you go north from Nice into the Alpes towards Chamonix and across Switzerland, rather than going across northen italy.
There are some nice minor roads in the area of Italy you're looking at, BUT if you limited on time and travelling on main roads you'll soon get sick of the traffic - I know I did.
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