French bikers are a very friendly community, especially when you try to speak their language, as the rest of French (contrary to what many say, just start with Bonjour and try your best).
I changed my Chain Kit (D.I.D.) in "Moto Expert" in Perpignan -first big town before the Spanish border- and they were nice, tried their best to have it done quickly and offered reasonable prices. They sell accesories and go for light mechanics (installing them and so on), so guess it it could be a good place for your tires (ask first, please).
Otherwise, in Barcelona area you'll find anything.
BTW, go to the decathlon in Perpignan if you look outdoor gear, it is MASSIVE.
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