Hi , there are daily ships from piraeus to chios island. I think two during summer period. One early in the morning and one in the afternoon. The ship to cesme leaves at 8 in the moning and takes about 45min-1hour. Last year it was the only possible cross for passengers and moto-cars between greece-turkey. From the other islands, are only for passengers. You don't have to book in advance for the ferries. The afternoon ship from pireaus arrives at chios about 3-4 at the night so you can wait few hours and catch the other one. In my opinion if you want to go north better ride from the mainland. If you want to go south take the ferry. The best part for me is from cesme down coast up to Kas. Really beautiful with great beaches. Ride safe
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