Hi Frush. I entered into Bolivia last year through the Ollagüe border crossing on my way to Uyuni.
There is nothing around Ollagüe, nothing at all.
There is only 1 petrol station between Ollagüe and Uyuni. It's in San Cristóbal.
The second question, there's a hostel in Alota called Hospedaje Los Andes, and another one in San Cristóbal called Hotel Sureño.
I hope this will help. In case you need more info, just make me know.
Regards from Spain.
Jorge.
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