I rode through every country in South America from 2012 to 2020. You can buy blanket coverage for all the southern South American countries (that includes one free tow) online from an Argentine company called ATM Seguros. If the online application rejects your passport number (like mine did) you can correspond with a human in head office who will process it for you. In French Guiana, coming from Suriname, there was an office that sold insurance 1 block from the control point. Going the other way, from Brazil, there is no office, but I did an online search and found a company in Italy called Mototouring s.r.l. that issued me a "carta verde" online. It was accepted by the French officials, who, by the way, also checked its expiry date on the way OUT of the country!
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