Sorry Jonathan - I don't think it's possible at the moment. The Visemar which used to sail from Venice to Alex is cancelled. The website says they may resume the service but having spoken to them a number of times they say not. The only other option I am aware of having done weeks of research is Grimaldi freighter cruises from Italy into Israel. This does stop at Greece and Turkey but there are no facilities to load/unload cars at either. It also stops at Alex but no embarkation/disembarkation permitted. But Israel will be a non starter for you if you are planning to go via Sudan for example. Options for now are overland via Syria - still probably possible but with obvious risks (check out the Middle east regional forum for info) or putting it into a container to Alex. Unfortunately Alex is a nightmare destination for a container (corruption/hasslewise).
Or you could go down the west coast - ferry to Morocco.
If you are planning to travel to southern Africa I would ship the car to somewhere like Walvis Bay Namibia and drive back - but of course that may not fit your plans.
Sorry to be so negative. It is a big headache for anyone wanting to drive to Africa from Europe overland at present.
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