Our method of "seeing" a country is to skip every second point of interest because that gives us a reason to go back - so we also missed a lot of the border crossings down the length of Chile. The main ones used by all the trucks and tour buses aren't of much interest anyway so we will get around to the other isolated border crossings in due course.
No idea about fuel on the de jama road. Certainly available in San Pedro if you can find the service station but we didn't desperately need it and lack of working ATMs meant we couldn't buy much anyway as I didn't want to waste USD changing into Chilean Pesos, so after getting the usual wrong directions from the locals we pushed on to the nearby provincial capital and stocked up.
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